INEB
INEB
TitleEffect of chemical composition on hydrophobicity and zeta potential of plasma sprayed HA/CaO-P 2O 5 glass coatings
Publication TypeJournal Article
2001
AuthorsFerraz, MP, Monteiro, FJ, Serro, AP, Saramago, B, Gibson, IR, Santos, JD
JournalBiomaterialsBiomaterials
Volume22
Issue23
Pagination3105 - 3112
Date Published2001///
01429612 (ISSN)
Adhesion, alloy, analytic method, article, bovine serum albumin, Calcium Compounds, calcium oxide, chemical composition, Chemical modification, Coatings, Composition, computer program, Contact angle, Durapatite, glass, hydrophobicity, hydroxyapatite, Hydroxyapatite glass composites, oxide, Oxides, pentoxide, Phosphorus Compounds, priority journal, protein, Serum Albumin, Bovine, Sprayed coatings, Surface charge, Surface Properties, Surface tension, Surface tension zeta potential, time, unclassified drug, Water, wettability, Wetting, X-Ray Diffraction, Zeta potential
Multilayered plasma sprayed coatings on the surface of Ti-6Al-4V alloys have been prepared, which were composed of an underlayer of HA and a surface layer of a CaO-P 2O 5 glass-HA composite, with 2 or 4 wt% of glass. Contact angle and surface tension variation with time, for both water and a protein solution, were determined by the sessile and pendent drop methods respectively using the ADSA-P software. Wettability studies showed that hydrophobicity of the coatings increase with the glass addition. The work of adhesion of albumin was also altered in a controlled manner by the addition of the CaO-P 2O 5 glass, being lower on the composite coatings than on HA. Zeta potential (ZP) results showed that composite coatings presented a higher net negative charge than HA coatings and that ZP values were also influenced by the content of the glass. This study demonstrated that the surface properties of those coatings may be modified by the addition of CaO-P 2O 5 glass. © 2001 Published by Elsevier Science Ltd.
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